Product ID:GAS, PREM UNLEADED
MSDS Date:05/31/1989
FSC:9130
NIIN:00-148-7104
MSDS Number: BKSJF

ASHLAND PETROLEUM CO DIV OF ASHLAND OIL INC

1409 WINCHESTER AVE
ASHLAND, KY 41114
US

Emergency Phone: 800-274-5263

Info Phone: 606-329-3333

Cage: 81355

STOP-N-GO 0F MADISON

391 ASHLAND, KY 41114 US

Telephone: 800-622-6846

Cage: STOPN

GASOLINE

CAS: 8006-61-9

RTECS: LX3300000

Fraction By Weight: >95%

OSHA PEL 300 PPM/500 STEL

ACGIH TLV: 300 PPM/500STEL;9192

BENZENE (SARA III)

CAS: 71-43-2

RTECS: CY1400000

Fraction By Weight: 1-5%

OSHA PEL 1PPM/5STEL;1910.1028

ACGIH TLV: 10 PPM; A2; 9192

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

THE MANUFACTURER LISTS THE FIRST 2 INGREDIENTS THEN UNDER

RTECS: 9999999ZZ

TOLUENE (SARA III)

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 3-7%

OSHA PEL 200 PPM/150 STEL

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

XYLENES (O-,M-,P- ISOMERS) (SARA III)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 4.6-11%.

OSHA PEL 100 PPM/150 STEL

ACGIH TLV: 100 PPM/150STEL;9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

1,2,4-TRIMETHYLBENZENE (SARA III)

CAS: 95-63-6

RTECS: DC3325000

Fraction By Weight: 1-4%

OSHA PEL 25 PPM

ACGIH TLV: 25 PPM; 9192

LD50 LC50 Mixture:NO INFORMATION GIVEN BY MFR ON THE MSDS.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:ACUTE:MATERIAL IS SLIGHTLY IRRITATING
TO BODY TISSUEES. INHALED OR INGESTED IT DEPRESSES THE CENTRAL
NERVOUS SYSTEM. CHRONIC:REPEATED OR PROLONGED EXPOSURE TO BENZENE,
EVEN AT RELATIVELY LOW CONCENT RATIONS, MAY RESULT IN VARIOUS BLOOD
DISORDERS RANGING FROM ANEMIA TO LEUKEMIA.
Explanation of Carcinogenicity:BENZENE IS LISTED BY ALL ABOVE AGENCIES
AS CARCINOGENIC.
Effects of Overexposure:EYE: MAY CAUSE SEVERE IRITATION, REDNESS,
TEARING, BLURRED VISION; SKIN: PROLONGED CONTACT MAY CAUSE MODERATE
IRRITATION, DEFATTING, DERMATITIS; INHALE: NASAL AND RESPIRATORY
IRRITATION, DIZZINESS, WE AKNESS, FATIQUE, NAUSEA, ETC.; INGEST:
GASTROINTESTINAL IRRITATION, NAUSEA, VOMITING, DIARRHEA, OR
ASPIRATION.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:SKIN: WASH WITH SOAP AND WATER, REMOVE & LAUNDER CONTAMINATED
CLOTHING; EYE: FLUSH WITH LARGE AMOUNTS OFWATER, LIFTING UPPER AND
LOWER LIDS OCCATIONALLY, GET MEDICAL ATTENTION; INHALE: REMOVE TO
FRESH AIR. ADMINISTER OXYGEN IF NECESSARY. GIVE ARTIFICIAL
RESPIRATION IF BREATHING HAS STOPPED; INGEST: DO NOT INDUCE
VOMITING. KEEP PERSON WARM, QUIET. GET MEDICAL ATTENTION.

Flash Point Method:TCC
Flash Point:-40F/-40C
Lower Limits:1.5
Extinguishing Media:USE CARBON DIOXIDE, REGULAR FOAM, OR DRY CHEMICAL.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS WITH A
FULL FACEPIECE OPERATED IN THE POSITIVE PRESSURE DEMAND MODE WHEN
FIGHTING FIRES.
Unusual Fire/Explosion Hazard:MATERIAL IS HIGHLY VOLATILE & READILY
GIVES OFF VAPORS WHICH MAY TRAVEL ALONG THE GROUND OR BE MOVED BY
VENTILATION & IGNITED BY PILOT LIGHTS, SPARKS, ETC.

Spill Release Procedures:ELIMINATE IGNITION SOURCES. SMALL SPILL:ABSORB
LIQUID ON PAPER, VERMICULITE, FLOOR ABSORBENT, ETC, AND TRANSFER TO
HOOD. LARGE SPILL:DIKE AREA TO CONTAIN. PUMP LIQUID TO SALVAGE TANK
FOR LATER DISPOSA L.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP AWAY FROM HEAT,SPARKS & OPEN
FLAME. KEEP CONTAINERS CLOSED. USE & STORE ONLY W/ADEQUATE
VENTILATION. GROUND CONTAINERS WHEN TRANSFERRING PRODUCT.
Other Precautions:DO NOT TRANSFER TO UNLABELED CONTAINERS. DO NOT USE
CUTTING OR WELDING TORCH ON THIS CONTAINER. KEEP OUT OF REACH OF
THE CHILDREN.

Respiratory Protection:USE A NIOSH/MSHA APPROVED AIR SUPPLIED
RESPIRATOR IF TLV IS EXCEEDED. OSHA REGULATIONS ALSO PERMIT OTHER
NIOSH/MSHA RESPIRATORS UNDER CERTAIN CONDITIONS. ENGINEERING OR
ADMINISTRATIVE CONTROLS SHOULD BE IMPLEMENTED TO CONTROL
EXPOSURES.
Ventilation:PROVIDE SUFFICIENT MECHANICAL VENTILATION AND/OR LOCAL
EXHAUST TO KEEP BELOW TLV.
Protective Gloves:NEOPRENE, NITRILE RUBBER TYPES.
Eye Protection:CHEM SPLASH GOGGLES OR SAFETY GLASSES
Other Protective Equipment:IMPERVIOUS CLOTHING AND BOOTS WHEN NEEDED TO
PREVENT PROLONGED OR REPEATED SKIN CONTACT.
Work Hygienic Practices:MFR: ? HMIS:USE GOOD INDUSTRIAL HYGIENE
PRACTICE. AVOID UNNECESSARY CONTACT. WASH THOROUGHLY BEFORE EATING
OR DRINKING.
Supplemental Safety and Health
NONE

HCC:F2
NRC/State Lic Num:NONE
Boiling Pt:B.P. Text:70F/21C
Vapor Pres:500 MMHG
Vapor Density:4.0
Spec Gravity:0.74
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:CLEAR LIQUID.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:NO INFORMATION GIVEN BY MFR ON THE MSDS.
Hazardous Decomposition Products:CARBON MONOXIDE AND CARBON DIOXIDE

Waste Disposal Methods:PREVENT RUNOFF TO SEWERS, STREAMS OR OTHER
BODIES OF WATER. IF RUNOFF OCCURS, NOTIFY AUTHORITIES. SMALL SPILL
TO BE EVAPORATED IN HOOD. LARGE SPILL TO BE DESTROYED BY LIQUID
INCINERATION.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.